Sorry, all I can do at this point is link you to my prefs file to copy: uk.co.introversion.defcon.prefs
What you can do is take it to the steam forums and ask around where you need to put it, or maybe PM some people here who seem to be using the Mac Steam version.
Also, you may want to contact the graphics card vendor (nvidia?) about the crash; they typically have an interest in these things, and I couldn't see anything immediately wrong in the lowest function of Defcon itself.
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